Stability of arsenopyrite and As(III) in low-temperature acidic solutions   总被引：1，自引：0，他引：1  

YU Yunmei  ZHU Yongxuan & GAO Zhenmin Key Laboratory of Ore Deposit Geochemistry  Chinese Academy of Sciences  Guiyang  China 《中国科学D辑(英文版)》2004,47(5)

Arsenopyrite is one of the most important pri-mary arsenic mineral. In the Eh-pH diagram of the As-O2-S-H2O system, if the total arsenic concentration (TAs) is taken to be 0.75 mg/L, the total sulfur con-centration, 32 mg/L, the temperature, 25℃and the pressure, one atmosphere pressure for the discrimina-tion of arsenic species, it may be found that under hy-pergene conditions, arsenopyrite is a moderately stable mineral. Only in the strongly alkaline and reducing environment can arsenopy…  相似文献   

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene     

Richard Winterhalter  Peter Neeb  Dirk Grossmann  Antje Kolloff  Osamu Horie  Geert Moortgat 《Journal of Atmospheric Chemistry》2000,35(2):165-197

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.  相似文献   

保持主分量变换结果信息的量化方法     

李超群朱宝山  朱述龙 《测绘学院学报》2005,22(3):175-177

从主分量变换后图像信息保持的角度出发，充分分析了变换结果存储导致信息丢失的原因；同时以直接线性变换为基础，提出了另外两种新的对主分量变换结果进行量化的方法；并对这3种方法进行了充分的比较，文中最后以信息熵为指标评价了3种方法的优劣。  相似文献   

The method of design for seismic data database system based on tree structure     

王喜珍  滕云田  高孟潭  陈步云  姜慧 《地震学报(英文版)》2005,18(1):99-105

Introduction In recent years, with the development of earthquake observation technology, increasing ofobservation stations and improvement of observation instruments which are digitalized and con-nected by network, a great deal of data is recorded, to some extend, which brings difficulty for usto manage and store them. It leads to traditional methods, which use the file system to managemass data, could not satisfy our requirement, and it is necessary to find a new method in place oftradit…  相似文献   

基于MAPGIS明码文件的绘图转换系统开发及应用   总被引：4，自引：1，他引：4  

段青梅  龙文华  丁天才  张玉宝  刘金宝 《物探与化探》2005,29(1):50-52,56

介绍了基于MAPGIS明码文件开发出的MAPGIS明码格式转换系统软件的结构及功能,并说明该软件在地球物理、地球化学领域中的应用。  相似文献   

用等效磁源法进行磁异常转换   总被引：1，自引：0，他引：1  

于德武 《物探化探计算技术》2004,26(2):133-135

用等效磁源法实现常规磁异常换算(延拓、求导、假重力异常换算、化磁极)的模型计算算例显示了等效源法在使用上的灵活性和方便性。与频率域换算方法相比,说明了等效源法换算结果更优于频率域换算结果。  相似文献   

采样过程和模数转换对记录的影响及“真实地面运动”获取——地震学上用的数字信号处理的基本原理和实例(讲座3)     

陈祥熊  江燕 《地震地磁观测与研究》1998,(2)

通过采样过程和模数转换对记录影响的分析,讨论了数字地震仪记录的动态范围,以及如何使用谱分析方法去除仪器对最终记录的影响,以便获取“真实地面运动”的近似。  相似文献   

GPS技术在金川露天矿边坡变形监测中的应用   总被引：6，自引：0，他引：6  

郑国忠  徐嘉谟 《工程地质学报》1998,6(3):282-288

本文结合金川露天矿边坡变形GPS监测研究,主要论述监测基点的选择,基点WGS-84坐标的确定,变形监测网的布设,GPS数据采集、处理和质量,坐标转换的实施等,给出反演推出的若干四等三角点及其它控制点的变形数据,这些数据和造成变形的物理成因符合得很好,最后概括出GPS技术应用于变形观测的若干优点。  相似文献   

The Persian calendar for 3000 years     

Kazimierz M. Borkowski 《Earth, Moon, and Planets》1996,74(3):223-230

Using the analytical theory of the motion of the Earth around the Sun the times of the vernal (Spring) equinox has been calculated over the period from the Hijra (AD 622) to AD 3800. These data alone allow to decide whether a particular Persian (or Jalaali) calendar year is common or leap. Presented analysis shows that an algorithm implemented in the so called Khayam program is valid for the year 1799 to 2256 (1178 to 1634 Jalaali). A concise algorithm has been worked out that reconstructs the pattern of leap years over time span of about 3000 years. FORTRAN routines for conversion between the Jalaali, Gregorian and Julian calendars and the Julian Day Number are presented.  相似文献   

9608号台风登陆北上总能量变化及渤海高压维持   总被引：10，自引：1，他引：9  

晁淑懿  仇永炎  汪迎辉 《气象》1998,24(6):3-10

首先分析了属于台风与西风槽的相互作用型的９６０８号台风在其登陆泊台风核心区总能量及其组成部分的变化。结果指出,决定总能量再度增长的主要是潜热能,而此时潜热能的增长是同台风东侧低层偏南急流有密度关系。台风的东北象限内潜热能增长最盛,特大暴雨区恰也在这个象限。其次利用对流层高层散度风场与旋转风场的配置,从散度风动勇与旋转风动能之间的转换关系,半定量地估计台风东侧黄海、渤海、日本海高压上空反气旋环流的增  相似文献